I've recently bought a mi Android TV 4A, I just want command using Google Assistant my TV when it is turned off. I've also noticed that is impossible to get linked using Chromecast connection if my TV is off, Google Assistant is not able to reach the device. So, in other words, if the TV is off , it is dead. I have been using Chromecast for years and I am able to do that (thanks to HDMI-CEC), and I just want it behaves like an external Chromecast device. It is possible to achive that? Thanks.
No... It won't be possible without an external stick as the TV totally turns off the WiFi module (as I understand) when powered off. Only way is to keep the TV in standby/sleep mode, if your TV allows that.